Product ID:SPRAY STENCIL INK, CH FREE, ALL COLORS
MSDS Date:04/29/1993
FSC:7510
NIIN:00N022902
MSDS Number: BZPVV

MARSH CO

707 EAST B ST
BELLEVILLE, IL 62222
US

Emergency Phone: 800-535-5053

Info Phone: 618-234-1122

Cage: GO822

MARSH COMPANY

388 BELLEVILLE, IL 62222 US

Telephone: 618-234-1122

Cage: 0MBZ9

HYDROCARBON PROPELLANT; (PROPANE/ISOBUTANE)

CAS: 68476-86-8

Fraction By Weight: 15-40%

OSHA PEL 1000 PPM (MFR)

ACGIH TLV: 900 PPM (MFR)

6900 MG/KG.

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 10-30%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENE (SARA 313) (CERCLA)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: <1%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM;150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

INGREDIENTS 6 - 9 HAVE NOT BEEN INTENTIONALLY INTRODUCED,

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

<100 PPM.

CAS: 7440-43-9

RTECS: EU9800000

Fraction By Weight: <0.1%

OSHA PEL 0.2 MG/M3 DUST

ACGIH TLV: 0.01 MG/M3 DUST

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

<100 PPM.

CAS: 7440-47-3

RTECS: GB4200000

Fraction By Weight: <0.1%

OSHA PEL 1 MG/M3

ACGIH TLV: 0.5 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

<100 PPM.

CAS: 7439-92-1

RTECS: OF7525000

Fraction By Weight: <0.1%

OSHA PEL SEE 1910.1025

ACGIH TLV: 0.15 MG/M3 DUST

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

<100 PPM.

CAS: 7439-97-6

RTECS: OV4550000

Fraction By Weight: <0.1%

OSHA PEL 0.1 MG/M3, C

ACGIH TLV: 0.025 MG/M3, S

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

725 G/L.

RTECS: 9999999VO

9750 MG/KG.

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 15-40%

OSHA PEL 1000 PPM

ACGIH TLV: 750 PPM;1000 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:VAPOR EXPOSURE MAY CAUSE SHORTNESS OF
BREATH, DIZZINESS, LIGHTHEADEDNESS, CENTRAL NERVOUS SYSTEM EFFECTS
OR LIVER & KIDNEY EFFECTS. VAPOR MAY IRRITATE EYES. PROLONGED SKIN
CONTACT CAN CAUSE IRRITATION , DEFATTING OF SKIN & POSSIBLY
DERMATITIS. NOTE:TOLUENE, LEAD & MERCURY APPEAR ON THE NAVY LISTING
OF (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:OCCUPATIONAL CHEMICAL REPRODUCTIVE
HAZARDS. SEEK CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS
CONCERNING LATEST HAZARD LIST INFORMATION & SAFE HANDLING &
EXPOSURE INFORMATION .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES & SEEK MEDICAL
ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING. WASH SKIN W/SOAP &
WATER. INHAL:REMOVE TO FRESH AIR, IF DISCOMFORT PERSISTS, SEEK
MEDICAL ATTENT ION. INGEST:DO NOT INDUCE VOMITING, CALL MD
IMMEDIATELY.

Flash Point:-50F,-46C
Lower Limits:1.2%
Upper Limits:12.8%
Extinguishing Media:WATER FOG, CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EXPOSURE TO HEAT OR TEMPERATURE >120F MAY
CAUSE CANS TO EXPLODE RELEASING HIGHLY FLAMMABLE PROPELLANT.

Spill Release Procedures:ISOLATE FROM SOURCES OF IGNITION. VENTILATE TO
REMOVE PROPELLANT VAPORS. CONTAIN SPILL USING SUITABLE ABSORBENT,
CONTAINERIZE IN AN APPROVED DOT CONTAINER FOR PROPER DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:EXPOSURE TO TEMPERATURE >120F MAY
CAUSE CONTAINER TO BURST, RELEASING HIGHLY FLAMMABLE PROPELLANT.
PROPELLANT VAPORS ARE HEAVIER THAN AIR.
Other Precautions:VENTILATE TO PVNT CONCS FROM REACHING FLAMM LEVELS.
FDA:(21CFR) THIS PROD DOES NO HAVE APPROVAL AS FOOD ADDITIVE,
EITHER DIRECT/INDIRECT. WHEN APPLIED TO OUTSIDE SURF OF FOOD
CNTNRS, CNTNR MUST BE FUN CTIONAL BARRIER SO THAT THERE IS(SUPDAT)

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR WHEN AIRBORNE
LEVELS MAY EXCEED PEL.
Ventilation:LOCAL EXHAUST: PREFERABLE. GENERAL EXHAUST: ACCEPTABLE.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . OTHER PROT CLTHG/EQUIP AS NEC TO
AVOID(SUPDAT)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SPEC GRAV:0.69-0.78 (H*2O=1). OTHER PREC:NO MIGRATION OF COMPONENTS OF
THIS PRODUCT TO FOOD. OTHER PROT EQUIP:PROLONGED CONTACT.

Boiling Pt:B.P. Text:>133F,>56C
Vapor Density:HVR/AIR
Spec Gravity:SUPP DATA
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NEGLIGIBLE
Appearance and Odor:VARIOUS AEROSOL COLORS W/AROMATIC ODOR.
Percent Volatiles by Volume:92-94

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, STRONG ALKALIES, STRONG MINERAL ACIDS.
Stability Condition to Avoid:TEMPERATURES >120F, SOURCES OF HEAT.
Hazardous Decomposition Products:CARBON MONOXIDE, TRACES OF PHOSGENE
FROM BURNING.
Conditions to Avoid Polymerization:AVOID EXPOSURE TO HEAT & FLAME.

Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE & FEDERAL
REGULATIONS. RCRA:(40CFR302.4) IT IS UP TO PRODUCT USER TO
DETERMINE, AT TIME OF DISPOSAL, IF MATERIAL SHOULD BE CLASSIFIED AS
A HAZARDOUS WASTE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.